Deer "jumping" the string is indeed a real factor, but as others have mentioned, they don't do it all the time. Over the decades I've been bowhunting, I've come to this conclusion about it....
I prefer, when at all possible, to have the deer I shoot an arrow at to be:
1. MOVING. Not running or even trotting, but in the process of taking a step, preferably the step that moves the near-side shoulder forward, exposing the vitals without the shoulder meat and leg bone in the way. Besides the obvious vital area exposure, when a deer is taking a step, that will give you maybe an extra second before he reacts enough to jump string enough to cause your arrow to go astray.
2. RELAXED, and unalerted. I want them in the mind set of not having a care in the world, other than where that next acorn or blade of grass is that they have their head down for. This will also gain you a precious moment or two before all hell breaks loose when the arrow is released.
This is also why I steer away now from using scents, and even calls many times when bowhunting, because a deer that's coming into a call, or a scent, is ON ALERT. He's LOOKING and paying attention to whats around him even more than normal.
This state of high alert, although not a "danger...get ready to flee" type alert, is still an alert, and when in this state they can go all that much the faster into the "I'mgettingthehelloutofhere" mode. Jumping the string is almost a guarantee at this point.
Now I've never shot a deer over a decoy, but I would imagine that if a buck is occupied with a decoy, that his attention is thus diverted, and this would also gain you some extra time before he could negatively react to your shot.

